全文获取类型
收费全文 | 672篇 |
免费 | 15篇 |
国内免费 | 6篇 |
专业分类
化学 | 410篇 |
晶体学 | 17篇 |
力学 | 13篇 |
数学 | 32篇 |
物理学 | 221篇 |
出版年
2023年 | 5篇 |
2021年 | 7篇 |
2020年 | 8篇 |
2019年 | 8篇 |
2018年 | 4篇 |
2017年 | 3篇 |
2016年 | 12篇 |
2015年 | 14篇 |
2014年 | 16篇 |
2013年 | 46篇 |
2012年 | 37篇 |
2011年 | 27篇 |
2010年 | 20篇 |
2009年 | 27篇 |
2008年 | 28篇 |
2007年 | 44篇 |
2006年 | 33篇 |
2005年 | 23篇 |
2004年 | 30篇 |
2003年 | 22篇 |
2002年 | 23篇 |
2001年 | 29篇 |
2000年 | 10篇 |
1999年 | 18篇 |
1997年 | 7篇 |
1996年 | 5篇 |
1995年 | 6篇 |
1994年 | 7篇 |
1993年 | 9篇 |
1992年 | 13篇 |
1991年 | 6篇 |
1990年 | 10篇 |
1989年 | 8篇 |
1988年 | 5篇 |
1987年 | 10篇 |
1986年 | 8篇 |
1985年 | 14篇 |
1984年 | 9篇 |
1983年 | 11篇 |
1982年 | 3篇 |
1981年 | 5篇 |
1980年 | 2篇 |
1979年 | 12篇 |
1978年 | 9篇 |
1977年 | 4篇 |
1976年 | 7篇 |
1975年 | 5篇 |
1974年 | 5篇 |
1973年 | 7篇 |
1967年 | 4篇 |
排序方式: 共有693条查询结果,搜索用时 24 毫秒
21.
Well‐Defined Iron Complexes as Efficient Catalysts for “Green” Atom‐Transfer Radical Polymerization of Styrene,Methyl Methacrylate,and Butyl Acrylate with Low Catalyst Loadings and Catalyst Recycling 下载免费PDF全文
So‐ichiro Nakanishi Dr. Mitsunobu Kawamura Hidetomo Kai Prof. Dr. Ren‐Hua Jin Dr. Yusuke Sunada Prof. Dr. Hideo Nagashima 《Chemistry (Weinheim an der Bergstrasse, Germany)》2014,20(19):5802-5814
Environmentally friendly iron(II) catalysts for atom‐transfer radical polymerization (ATRP) were synthesized by careful selection of the nitrogen substituents of N,N,N‐trialkylated‐1,4,9‐triazacyclononane (R3TACN) ligands. Two types of structures were confirmed by crystallography: “[(R3TACN)FeX2]” complexes with relatively small R groups have ionic and dinuclear structures including a [(R3TACN)Fe(μ‐X)3Fe(R3TACN)]+ moiety, whereas those with more bulky R groups are neutral and mononuclear. The twelve [(R3TACN)FeX2]n complexes that were synthesized were subjected to bulk ATRP of styrene, methyl methacrylate (MMA), and butyl acrylate (BA). Among the iron complexes examined, [{(cyclopentyl)3TACN}FeBr2] ( 4 b ) was the best catalyst for the well‐controlled ATRP of all three monomers. This species allowed easy catalyst separation and recycling, a lowering of the catalyst concentration needed for the reaction, and the absence of additional reducing reagents. The lowest catalyst loading was accomplished in the ATRP of MMA with 4 b (59 ppm of Fe based on the charged monomer). Catalyst recycling in ATRP with low catalyst loadings was also successful. The ATRP of styrene with 4 b (117 ppm Fe atom) was followed by precipitation from methanol to give polystyrene that contained residual iron below the calculated detection limit (0.28 ppm). Mechanisms that involve equilibria between the multinuclear and mononuclear species were also examined. 相似文献
22.
Shozo Kawamura Makoto Suzuki Hossain MD. Zahid Hirofumi Minamoto 《Applied Acoustics》2009,70(11-12):1393-1399
Machine condition monitoring and fault diagnosis of rotating machinery are very important because of the wide use of rotating machinery in industry. Couplings and gears are used in many mechanical systems to connect elements and transmit power. The system is usually modeled as a single-degree-of-freedom system with a piecewise linear spring property, where the mass of main machine is only considered. In the present study, the dynamic behavior of a system with an unsymmetrical nonlinearity and a significant mass of the connecting part was investigated both experimentally and by numerical simulation. In the experiment, a 1/3 sub-harmonic oscillation was observed, but this oscillation was not found in the simulation using a single-degree-of-freedom system, in which the mass of the connecting part was ignored. However, when a two-degrees-of-freedom system was used that considered both the mass of the connecting part and the impact property, the 1/3 sub-harmonic oscillation was observed. Thus it is recognized that an adequate mathematical model for diagnosis in the early stage of abnormality must be selected on the basis of the mass ratio between the connecting part and the main body. 相似文献
23.
24.
Byungchan Bae Shinya Kawamura Kenji Miyatake Masahiro Watanabe 《Journal of polymer science. Part A, Polymer chemistry》2011,49(17):3863-3873
Random and multiblock sulfonated poly(arylene ether sulfone)s (SPEs) containing various azole groups such as oxadiazole and triazole were synthesized and characterized for fuel cell application. Successful preparation of SPE membranes depended on the structure of azole groups, which affected solubility of precursors and the resulting SPEs. Although oxadiazole groups were incorporated into hydrophobic component, they were found to be hydrophilic to give higher proton conductivity. Introduction of oxadiazole groups into random SPE gave comparable proton conductivity to that of Nafion NRE at >60% relative humidity at 80 °C. Block copolymer structure further increased the proton diffusion coefficient without increasing ion exchange capacity. Hydrolytic and oxidative stability of the SPE membranes was affected by both hydrophilic and hydrophobic components. Oxadiazole groups gave negative impact on hydrolytic and mechanical stability to the SPE membranes. © 2011 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2011 相似文献
25.
The combination of pivalic or acetic acid as a promoter and EtOAc as a solvent and acetyl donor proved to be efficient for the chemoselective N-acetylation of primary aliphatic amines to afford the corresponding acetamides. We developed a simple and convenient approach, which requires mild reaction conditions. Competitive inter- and intramolecular reactions between aliphatic amines, alcohols, and aromatic amines were examined, and chemoselectivity was achieved by adjusting the conditions of the reaction. 相似文献
26.
Prof. Dr. Masaichi Saito Tomoki Akiba Misumi Kaneko Toshiaki Kawamura Dr. Minori Abe Prof. Dr. Masahiko Hada Prof. Dr. Mao Minoura 《Chemistry (Weinheim an der Bergstrasse, Germany)》2013,19(50):16946-16953
Plumbacyclopentadienylidenes, in which the lead atoms have divalent states and are coordinated by THF, pyridine and N‐heterocyclic carbene, were synthesized and characterized. The THF‐ and pyridine‐stabilized compounds can be regarded as rare examples of hypervalent 10‐X‐4 species. The equilibrium between the THF adduct and the free plumbacyclopentadienylidene was evidenced by spectroscopic analysis and theoretical calculations. The THF adduct in benzene converted into a plumbylene dimer, where one of the lead centers is coordinated by THF and the other lead atom is coordinated by a divalent lead atom, the dimer gradually decomposing into spiroplumbole. The THF adduct unexpectedly reacted with trifluoroborane and trichlorogallane to afford fluoroborole and chlorogallole, which are the first examples of non‐annulated fluoroborole and gallole, respectively. 相似文献
27.
28.
Uchiyama T Miyoki S Telada S Yamamoto K Ohashi M Agatsuma K Arai K Fujimoto MK Haruyama T Kawamura S Miyakawa O Ohishi N Saito T Shintomi T Suzuki T Takahashi R Tatsumi D 《Physical review letters》2012,108(14):141101
The thermal fluctuation of mirror surfaces is the fundamental limitation for interferometric gravitational wave (GW) detectors. Here, we experimentally demonstrate for the first time a reduction in a mirror's thermal fluctuation in a GW detector with sapphire mirrors from the Cryogenic Laser Interferometer Observatory at 17 and 18 K. The detector sensitivity, which was limited by the mirror's thermal fluctuation at room temperature, was improved in the frequency range of 90 to 240 Hz by cooling the mirrors. The improved sensitivity reached a maximum of 2.2×10(-19) m/√Hz at 165 Hz. 相似文献
29.
Suzuki M Kawamura N Miyagawa H Garitaonandia JS Yamamoto Y Hori H 《Physical review letters》2012,108(4):047201
We show that bulk gold (Au) exhibits temperature-independent paramagnetism in an external magnetic field by x-ray magnetic circular dichroism spectroscopy at the Au L(2) and L(3) edges. Using the sum-rule analysis, we obtained a magnetic moment of 1.3 × 10(-4) μB/atom in an external magnetic field of 10 T and a paramagnetic susceptibility of 8.9 × 10(-6) for the 5d orbit. The induced paramagnetism in bulk Au is characterized by a large (≈ 30%) orbital contribution. This orbital component was retained even when Au atoms formed nanoparticles, playing an important role in stabilizing the spontaneous spin polarization in the Au nanoparticles. 相似文献
30.
静止水中单个上升气泡的直接数值模拟 总被引:5,自引:2,他引:3
本文发展了基于Front Tracking的直接数值模拟方法研究气液两相界面的迁移特性,该方法对气液两相采用半隐式的分步法直接求解N-S方程,耦合Front Tracking Method获得两相界面的三维变形。针对无边界以及垂直壁面附近静止水中的单个气泡上升过程进行模拟,研究气泡运动的机理以及气泡与壁面的相互作用。数值模拟准确再现了气泡的上升过程和变形,不同Re数下气泡的上升速度计算结果同经验关联式非常吻合,验证了该方法的有效性。随后分析了气泡周围流场的结构,发现壁面对气泡周围流场的抑制是壁面对气泡作用力的主要原因,将导致气泡逐渐偏离垂直壁面。 相似文献